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There is
less literature and information available regarding CCA-treated
timber impacts on marine wasters, where it is most commonly used
for marine piles. Townsend et al (2003) found that copper, rather
than arsenic, was most toxic for the aquatic environment. However,
when copper was present in the CCA combination, it appeared to be
more toxic than when it was on its own, raising concerns about the
effects of the combination of copper, arsenic and chromium.
Weis and
Weis (2004) point out that the “deleterious effects”
of CCA-treated timber on many aquatic organisms have been well documented.
The heavy metals, particularly the copper, accumulates in the sediments
near the wood and in the organisms, particularly those that live
in the sediments or attach themselves to the wood. The metals can
then bioaccumulate up the food chain. Impacts include reduced growth,
altered behaviour and mortality at the individual level, and reduced
numbers and diversity at the community level. They note that any
alternative preservative to CCA would still be harmful to an aquatic
environment if it contained copper.
Initial
research findings from the CSIRO into bio-acculumation of CCA in
barnacles has found that barnacles on CCA-treated marine piles have
elevated heavy metal levels, although barnacles on adjacent untreated
piles do not have elevated levels. Barnacles on piles treated with
CCA then sealed in by creosote have not been found with elevated
levels of arsenic, although they do have slightly higher levels
of copper (Cookson, L., CSIRO Forestry and Forest Products, Pers.
Comm., 14/12/04).

References:
Townsend,
T., Stook, K., Ward, M., Solo-Gabrielle, H. (2003) ‘Leaching
And Toxicity Of CCA-Treated And Alternative-Treated Wood Products’,
Florida Center For Solid And Hazardous Waste Management, Report
#02-4
Weis,
J.S. and Weis, P. (2004), ‘Effects of CCA Wood on Non-Target
Aquatic Biota’, Environmental Impacts of Preservative-Treated
Wood Conference, Orlando, February. http://www.ccaresearch.org/Pre-Conference/pdf/Weis.pdf

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